特性:
氮化硼是由氮原子和硼原子構(gòu)成的晶體,該晶體結(jié)構(gòu)分為:六方氮化硼(hbn)、密排六方氮化硼(wbn)和立方氮化硼,其中六方氮化硼的晶體結(jié)構(gòu)具有類似的石墨層狀結(jié)構(gòu),呈現(xiàn)松散、潤滑、易吸潮、質(zhì)輕等性狀的白色粉末,所以又稱“白色石墨”。理論密度2.27g/cm3,比重:2.43,莫式硬度為2.六方氮化硼是具有良好的電絕緣性,導(dǎo)熱性,化學(xué)穩(wěn)定性,無明顯熔點,在0.1mpa氮氣中3000℃,在中性還原氣氛中,耐熱到2000℃,在氮和氬中使用溫度可達(dá)到2800℃,在氧氣氣氛中穩(wěn)定性較差,使用溫度1000℃以下。六方氮化硼的膨脹系數(shù)相當(dāng)于石英,但導(dǎo)熱率是石英的十倍。在高溫時也具有良好的潤滑性,是一種優(yōu)良的高溫固體潤滑劑,有很強(qiáng)的中子吸收能力,化學(xué)性質(zhì)穩(wěn)定,對幾乎所有熔融金屬都具化學(xué)惰性。
六方氮化硼不溶冷水,水煮沸時水解非常緩慢并產(chǎn)生少量的硼酸和氨,與弱酸和強(qiáng)堿在室溫下均不起反應(yīng),微溶于熱酸,用熔融的氫氧化鈉,氫氧化鉀處理才能分解。對各種無機(jī)酸、堿、鹽溶液及有機(jī)溶劑均有相當(dāng)?shù)目垢芰Α?/p>
characteristic:
amorphous boron is a kind of black or brown powder. active inchemicl proprety,boron is odourless with the density of 1.73. inthe air and normal temperature,it is stable. when heatedto300℃,amorphous boron can beoxidized.when heated to700℃,it can be combustible,and theflame takes on the color of red.however,the flame looks green whenboron is slighely gasified
boron does not dissolve in water ,hydrochloric acid, ethylalcohol,ether,sulphuric acid,nitric aicid and moltten metales. athigh temperature,baron interacts withoxygen,nitrigen,sulphur,halogen and carbon.it also combines withnany metals directly to form metal compounds.in addition,itnteracts with organic compounds to form organic baronsynthesis.
產(chǎn)品等級
主含量
游離
氧化硼
粒度
(d50)(μm)
特級品
≥99%
≤0.4%
0.5—3.0
一級品
≥98%
≤0.5%
0.5—3.0
二級品
≥97%
≤0.5%
0.5—3.0
包裝:1公斤/鋁鉑紙袋
10公斤/紙箱
20公斤/紙箱
technicalbatch standard :
contents of bn
b2o3
granularity
(d50)(μm)
≥99%
≤0.4%
0.5—3.0
≥98%
≤0.5%
0.5—3.0
≥97%
≤0.5%
0.5—3.0
packing:1kg/bag
10kg/carton
20kg/carton
氮化硼參數(shù):
1、高耐熱性:3000℃升華,其強(qiáng)度1800℃為室溫的2倍,1500℃空冷至室溫數(shù)十次不破裂,在惰性氣體中2800℃不軟化。
2、高導(dǎo)熱系數(shù):熱壓制品為33w/m.k和純鐵一樣,在530℃以上是陶瓷材料中導(dǎo)熱Zui大的材料。
3、低熱膨脹系數(shù):2×10-6的膨脹系數(shù)僅次于石英玻璃,是陶瓷中Zui小的,加上其具有高導(dǎo)熱性,所以抗熱震性能很好。
4、優(yōu)良的電性能:高溫絕緣性好,25℃為1014ω-cm,2000℃還可以達(dá)到103ω-cm,是陶瓷中的高溫絕緣材料,擊穿電壓3kv/mv,低介電損耗108hz時為2.5×10-4,介電常數(shù)為4,可透微波和紅外線。
5、良好的耐腐蝕性:與一般金屬(鐵、銅、鋁、鉛等)、稀土金屬,貴重金屬,半導(dǎo)體材料(鍺、硅、砷化鉀),玻璃,熔鹽(水晶石、氟化物、爐渣)、無機(jī)酸、堿不反應(yīng)。
6、低的摩擦系數(shù):u為0.16,高溫下不增大,比二硫化鉬,石墨耐高溫,氧化氣氛可用到900℃,真空下可用到2000℃。
7、高純度含硼高:其雜質(zhì)含量小于10ppm,而含硼大于43.6%。
8、可機(jī)械加工性:其硬度為莫氏2,所以可用一般機(jī)械加工方法加工成精度很高的零部件制品。
high heatresistance: bn’s sublimation is 3000℃; its intensity is 1800℃which is twice as room temperature; dcadetimes of non-rupture from 1500℃air-cooled to roomtemperature; non-soften at 2800℃in inert gas.
high thermal conductivity: its thermal conductivity as hotembossing products is 33w/m.k, which is same as pure iron. amongceramic materials whose thermal conductivity are above530℃, boronnitride is the best materialin terms of thermal conductivity.
low coefficient of thermal expansion: the coefficient of thermalexpansion of bn is 2*10-6, which is only preceded byquartz glass. bn’s thermal expansion is the lowest among ceramicmaterials. the thermal shock resistance of bn is also brilliant asthe results of its high thermal conductivity and low thermalexpansion.
excellent electrical properties: its high-temperature insulation isexcellent; its insulation are 1014ω-cm at 25℃and 103ω-cmat 2000℃. bn is the best high temperature insulationmaterial among ceramic materials; its breakdown voltage is 3kv/mm;its insulation is 2.5*10-4when the low dielectric loss is 108hz;its permittivity is 4. bn also can pass through microwave andinfrared.
high corrosion resistance: bn does not react with general metals(iron, copper, aluminum, lead and so on), rare earth metals,precious metals, semiconductor materials (germanium, silicon,potassium arsenide), glass, molten salt (crytal stone, fluoride,slag), inorganic acid and alkali.
low coefficient of friction: the u of bn is 0.16, which will notfurther enlarge in high temperature, and it is much better thanmolybdenum disulfide and graphite. bn can be used at900℃in oxidation atmosphere and at2000℃in vacuum.
high purity with high b: its impurity conten < 10ppm, and itscontent of b > 43.6%.
machinery processing: its mohs hardness is 2. therefore, bn can beused to process high precision parts and components by normalprocessing skill
應(yīng)用范圍:
☆氮化硼是一種無毒、耐高溫、耐腐蝕、高導(dǎo)熱、高絕緣,潤滑性能優(yōu)良的材料。
☆既是電絕緣體又是熱導(dǎo)體,高溫狀態(tài)下的特殊電解、電阻材料,高壓高頻電及等離子弧的絕緣體。
☆可作為半導(dǎo)體的固相摻雜材料、抗氧化或抗水的潤滑脂。
☆高溫潤滑劑和模型的脫模劑,氮化硼粉末還可以作為玻璃微珠的防粘劑,玻璃和金屬成型的脫模劑。
☆由氮化硼加工制成的超硬材料,可制成高速切割工具和地質(zhì)勘探、石油鉆探的鉆頭。
☆原子反應(yīng)堆的結(jié)構(gòu)材料,飛機(jī)、火箭發(fā)動機(jī)的噴,防止中子輻射的包裝材料,航天航空中的熱屏蔽材料。
☆無毒無害又具有潤滑性,可用作化妝品的填料。
☆在觸媒參與下,經(jīng)高溫高壓處理可轉(zhuǎn)化為堅硬如金剛石的立方氮化硼。
☆做各種電容器薄膜鍍鋁、顯像管鍍鋁、顯示器鍍鋁等的蒸發(fā)舟。
☆晶體管的熱封干燥劑和塑料樹脂等聚合物的添加劑。
☆各種激光防偽鍍鋁、商標(biāo)燙金材料,各種煙標(biāo),啤酒標(biāo)、包裝盒,香煙包裝盒鍍鋁等等。
productapplications:
boronnitride is an excellent material of high—temperature resistance,corrosion resistance, thermal conducting, insulating andlubrication. it is widely used in petroleum, chemicals, machinery,electronics, electric power, textile, nuclear industry, spacetechnology and many other industry fields. as a multifunctionalmaterial, it is also applied to the insulator of high voltage,uency and plasma arc insulator, solid doping material ofsemi—conductor, structual material of nuclear reactior, packingmaterial of neutral radiant resistance, lubricant of hightemperature resistance, drawing pattern agent of moulds,and greaseof anti—oxidization.in addition, the powder of boron nitride can beused as the anti—adhesive agent of glass beads,the drawing patternagent of glass and metal moulds. the last but not the least, thesuperhard material made of boron nitride can also be applied as thehigh speed cutting tools, the drill heads for geographicexploration and petroleum exploitation.
單體硼 ; 氮化硼 ; 無水硼砂 ; 硼酐 ; 六方氮化硼 ; 無水四硼酸鈉 ; 四硼酸鈉 ; 無定形元素硼 ; 硼粉
生產(chǎn)、經(jīng)營硼產(chǎn)品(除危險化學(xué)品)。(涉及許可經(jīng)營的,憑許可證經(jīng)營)(依法須經(jīng)批準(zhǔn)的項目,經(jīng)相關(guān)部門批準(zhǔn)后方可開展經(jīng)營活動。)
遼寧硼達(dá)科技有限公司是我國為數(shù)不多的能夠生產(chǎn)多種硼產(chǎn)品的專業(yè)生產(chǎn)企業(yè)。公司位于遼寧省營口市高新技術(shù)開發(fā)區(qū),依托我國最大硼礦產(chǎn)地,投資800萬,占地13000平方米,劇本大批量生產(chǎn)單體硼、無水硼砂、氮化硼、硼酐、硼粉、速溶硼等硼系列產(chǎn)品的能力,可按照客戶的要求生產(chǎn)各種含量各種等級的硼產(chǎn)品。企業(yè)以雄厚的生產(chǎn)技術(shù)和研發(fā)能力、先進(jìn)的檢測手段、優(yōu)良的產(chǎn)品質(zhì)量以及誠信為本,質(zhì)量為先的企業(yè)理念贏得市場,并以優(yōu)異的產(chǎn)品、優(yōu)質(zhì)的服務(wù)、優(yōu)惠的價格,與廣大新...